Oxygen‐18 dynamics in precipitation and streamflow in a semi‐arid agricultural watershed,Eastern Washington,USA     

Bryan G. Moravec  C. Kent Keller  Jeffrey L. Smith  Richelle M. Allen‐King  Angela J. Goodwin  Jerry P. Fairley  Peter B. Larson 《水文研究》2010,24(4):446-460

Understanding flow pathways and mechanisms that generate streamflow is important to understanding agrochemical contamination in surface waters in agricultural watersheds. Two environmental tracers, δ¹⁸O and electrical conductivity (EC), were monitored in tile drainage (draining 12 ha) and stream water (draining nested catchments of 6‐5700 ha) from 2000 to 2008 in the semi‐arid agricultural Missouri Flat Creek (MFC) watershed, near Pullman Washington, USA. Tile drainage and streamflow generated in the watershed were found to have baseline δ¹⁸O value of ?14·7‰ (VSMOW) year round. Winter precipitation accounted for 67% of total annual precipitation and was found to dominate streamflow, tile drainage, and groundwater recharge. ‘Old’ and ‘new’ water partitioning in streamflow were not identifiable using δ¹⁸O, but seasonal shifts of nitrate‐corrected EC suggest that deep soil pathways primarily generated summer streamflow (mean EC 250 µS/cm) while shallow soil pathways dominated streamflow generation during winter (EC declining as low as 100 µS/cm). Using summer isotopic and EC excursions from tile drainage in larger catchment (4700‐5700 ha) stream waters, summer in‐stream evaporation fractions were estimated to be from 20% to 40%, with the greatest evaporation occurring from August to October. Seasonal watershed and environmental tracer dynamics in the MFC watershed appeared to be similar to those at larger watershed scales in the Palouse River basin. A 0·9‰ enrichment, in shallow groundwater drained to streams (tile drainage and soil seepage), of δ¹⁸O values from 2000 to 2008 may be evidence of altered precipitation conditions due to the Pacific Decadal Oscillation (PDO) in the Inland Northwest. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Lacustrine records of post‐glacial environmental change from the Nulhegan Basin,Vermont, USA     

Jeffrey S. Munroe 《第四纪科学杂志》2012,27(6):639-648

The sedimentary records of Nulhegan Pond and Beecher Pond in the Nulhegan Basin of north‐eastern Vermont were analyzed to yield a history of environmental change since the latest Pleistocene. Shoreline landforms indicate that part of the Nulhegan Basin was inundated by Glacial Lake Nulhegan (GLN), which was impounded behind a dam of glacial sediment. Outwash derived from stagnant ice forms the bottom 176 cm of the Nulhegan Pond core. Fine‐grained inorganic sediment deposited between 13.4 and 12.2k cal a BP is interpreted as a deep‐water facies representing GLN, while coarser sediment from 12.2 to 11.8k cal a BP records draining of the glacial lake. Rapid, simultaneous increases in organic matter and biogenic silica signal the onset of productivity following the Younger Dryas. Beecher Pond formed c. 11.3k cal a BP through surface collapse over a buried ice block; buried stagnant ice may have persisted in the vicinity of the pond into the early Holocene. From 8.9 to 5.5k cal a BP, sediment in both lakes became coarser and richer in aquatic organic matter, suggesting a low‐water phase in which previously deposited lacustrine sediments were reworked and the littoral zone shifted basinward. Low water levels at this time are consistent with other records from Maine and southern Quebec, but contrary to records from ～325 km to the south. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Evaluation of an empirical orthogonal function–based method to downscale soil moisture patterns based on topographical attributes     

Frederick A. Busch  Jeffrey D. Niemann  Michael Coleman 《水文研究》2012,26(18):2696-2709

Soil moisture influences many hydrologic applications including agriculture, land management and flood prediction. Most remote‐sensing methods that estimate soil moisture produce coarse resolution patterns, so methods are required to downscale such patterns to the resolutions required by these applications (e.g. 10‐ to 30‐m grid cells). At such resolutions, topography is known to affect soil moisture patterns. Although methods have been proposed to downscale soil moisture based on topography, they usually require the availability of past high‐resolution soil moisture patterns from the application region. The objective of this article is to determine whether a single topographic‐based downscaling method can be used at multiple locations without relying on detailed local observations. The evaluated downscaling method is developed on the basis of empirical orthogonal function (EOF) analysis of space–time soil moisture data at a reference catchment. The most important EOFs are then estimated from topographic attributes, and the associated expansion coefficients are estimated on the basis of the spatial‐average soil moisture. To test the portability of this EOF‐based method, it is developed separately using four data sets (Tarrawarra, Tarrawarra 2, Cache la Poudre and Satellite Station), and the relationships that are derived from these data sets to estimate the EOFs and expansion coefficients are compared. In addition, each of these downscaling methods is applied not only for the catchment where it was developed but also to the other three catchments. The results suggest that the EOF downscaling method performs well for the location where it is developed, but its performance degrades when applied to other catchments. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Raman spectroscopic and calorimetric observations on natural gas hydrates with cubic structures I and II obtained from Lake Baikal     

Akihiro Hachikubo  Oleg Khlystov  Masato Kida  Hirotoshi Sakagami  Hirotsugu Minami  Satoshi Yamashita  Nobuo Takahashi  Hitoshi Shoji  Gennadiy Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2012,32(5-6):419-426

This study reports measurements of the Raman spectra of Lake Baikal gas hydrates and estimations of the hydration number of methane-rich samples. The hydration number of gas hydrates retrieved from the southern Baikal Basin (crystallographic structure I) was approx. 6.1. Consistent with previous results, the Raman spectra of gas hydrates retrieved from the Kukuy K-2 mud volcano in the central Baikal Basin indicated the existence of crystallographic structures I and II. Measurements of the dissociation heat of Lake Baikal gas hydrates by calorimetry (from the decomposition of gas hydrates to gas and water), employing the hydration number, revealed values of 53.7–55.5?kJ?mol^–1 for the southern basin samples (structure I), and of 54.3–55.5?kJ?mol^–1 for the structure I hydrates and 62.8–64.2?kJ?mol^–1 for the structure II hydrates from the Kukuy K-2 mud volcano.  相似文献   

Thermal anomalies associated with shallow gas hydrates in the K-2 mud volcano, Lake Baikal     

Jeffrey Poort  Oleg M. Khlystov  Lieven Naudts  Albert D. Duchkov  Hitoshi Shoji  Shin’ya Nishio  Marc De Batist  Akihiro Hachikubo  Masato Kida  Hirotsugu Minami  Andrey Y. Manakov  Marina V. Kulikova  Alexey A. Krylov 《Geo-Marine Letters》2012,32(5-6):407-417

Thermal measurements and hydrate mapping in the vicinity of the K-2 mud volcano in Lake Baikal have revealed a particular type of association of thermal anomalies (29–121?mW?m^–2) near hydrate-forming layers. Detailed coring within K-2 showed that hydrates are restricted to two distinct zones at sub-bottom depths exceeding 70–300?cm. Temperature data from stations with hydrate recovery and degassing features all display low thermal gradients. Otherwise, the thermal gradients within the mud volcano are generally increased. These findings imply a more complicated thermal regime than often assumed for mud volcanoes, with important roles for both fluids and hydrates. The coexistence of neighbouring low and high thermal anomalies is interpreted to result from discharging and recharging fluid activity, rather than hydrate thermodynamics. It is suggested that hydrates play a key role in controlling the fluid circulation pattern at an early stage. At a later stage, the inflow of undersaturated lake water would favour the dissolution of structure I hydrates and the formation of structure II hydrates, the latter having been observed on top of structure I hydrates in the K-2 mud volcano.  相似文献   

Geopolitics reframed: security and identity in Europe's eastern enlargement - by Merje Kuus     

Alex Jeffrey 《Area》2009,41(2):220-221

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Observed Spatial and Temporal Distributions of CVOCs at Colorado and New York Vapor Intrusion Sites     

David Folkes  William Wertz  Jeffrey Kurtz  Theodore Kuehster 《Ground Water Monitoring & Remediation》2009,29(1):70-80

The vapor intrusion impacts associated with the presence of chlorinated volatile organic contaminant plumes in the ground water beneath residential areas in Colorado and New York have been the subject of extensive site investigations and structure sampling efforts. Large data sets of ground water and indoor air monitoring data collected over a decade-long monitoring program at the Redfield, Colorado, site and monthly ground water and structure monitoring data collected over a 19-month period from structures in New York State are analyzed to illustrate the temporal and spatial distributions in the concentration of volatile organic compounds that one may encounter when evaluating the potential for exposures due to vapor intrusion. The analysis of these data demonstrates that although the areal extent of structures impacted by vapor intrusion mirrors the areal extent of chlorinated volatile organic compounds in the ground water, not all structures above the plume will be impacted. It also highlights the fact that measured concentrations of volatile organic compounds in the indoor air and subslab vapor can vary considerably from month to month and season to season. Sampling results from any one location at any given point in time cannot be expected to represent the range of conditions that may exist at neighboring locations or at other times. Recognition of this variability is important when designing sampling plans and risk management programs to address the vapor intrusion pathway.  相似文献   

Basal‐topographic control of stationary ponds on a continuously moving landslide     

Jeffrey A. Coe  Jonathan P. McKenna  Jonathan W. Godt  Rex L. Baum 《地球表面变化过程与地形》2009,34(2):264-279

The Slumgullion landslide in the San Juan Mountains of southwestern Colorado has been moving for at least the last few hundred years and has multiple ponds on its surface. We have studied eight ponds during 30 trips to the landslide between July 1998 and July 2007. During each trip, we have made observations on the variability in pond locations and water levels, taken ground‐based photographs to document pond water with respect to moving landslide material and vegetation, conducted Global Positioning System surveys of the elevations of water levels and mapped pond sediments on the landslide surface. Additionally, we have used stereo aerial photographs taken in October 1939, October 1940 and July 2000 to measure topographic profiles of the eight pond locations, as well as a longitudinal profile along the approximate centerline of the landslide, to examine topographic changes over a 60‐ to 61‐year period of time. Results from field observations, analyses of photographs, mapping and measurements indicate that all pond locations have remained spatially stationary for 60–300 years while landslide material moves through these locations. Water levels during the observation period were sensitive to changes in the local, spring‐fed, stream network, and to periodic filling of pond locations by sediment from floods, hyperconcentrated flows, mud flows and debris flows. For pond locations to remain stationary, the locations must mimic depressions along the basal surface of the landslide. The existence of such depressions indicates that the topography of the basal landslide surface is irregular. These results suggest that, for translational landslides that have moved distances larger than the dimensions of the largest basal topographic irregularities (about 200 m at Slumgullion), landslide surface morphology can be used as a guide to the morphology of the basal slip surface. Because basal slip surface morphology can affect landslide stability, kinematic models and stability analyses of translational landslides should attempt to incorporate irregular basal surface topography. Additional implications for moving landslides where basal topography controls surface morphology include the following: dateable sediments or organic material from basal layers of stationary ponds will yield ages that are younger than the date of landslide initiation, and it is probable that other landslide surface features such as faults, streams, springs and sinks are also controlled by basal topography. The longitudinal topographic profile indicated that the upper part of the Slumgullion landslide was depleted at a mean vertical lowering rate of 5.6 cm/yr between 1939 and 2000, while the toe advanced at an average rate of 1.5 m/yr during the same period. Therefore, during this 61‐year period, neither the depletion of material at the head of the landslide nor continued growth of the landslide toe has decreased the overall movement rate of the landslide. Continued depletion of the upper part of the landslide, and growth of the toe, should eventually result in stabilization of the landslide. Published in 2008 by John Wiley & Sons, Ltd.  相似文献   

Spatial modeling of annual minimum and maximum temperatures in Iceland     

Birgir Hrafnkelsson  Jeffrey S. Morris  Veerabhadran Baladandayuthapani 《Meteorology and Atmospheric Physics》2012,116(1-2):43-61

Bayesian hierarchical modeling is applied to the analysis of annual minimum and maximum temperatures. In both cases the generalized extreme value distribution is selected as the marginal distribution at each site due to its flexibility and theoretical basis. This distribution has three unknown parameters, a location parameter, a scale parameter and a shape parameter. The location and scale parameters are assumed to vary across sites while the shape parameter is assumed to be the same for all sites. The location and the scale parameters are modeled as two independent Gaussian spatial processes which are governed by the Matérn correlation function. These spatial processes play a central role in spatial predictions at unobserved sites. The location parameter is also modeled with a common time effect which includes a linear trend and a linear site effect with altitude, distance to open sea, latitude and longitude as covariates. This model allows for spatial predictions for any set of unobserved sites, the scale of the grid can be as fine as possible as long as the covariates are observed at each of the unobserved sites. Data on the annual minimum and maximum temperatures in Iceland from 1961 to 2009?at 72 sites are analyzed and used to predict the 2nd percentile of the minimum temperature for the 12-month period from July 2011 to June 2012 and the 98th percentile of maximum temperature for the year 2011 for a large set of unobserved sites across Iceland at which the covariates are available. The spatial predictions reveal that the 2nd percentile of minimum temperature for 2011 to 2012 reaches ?35°C in the central part of Iceland and ranges from ?12 to ?22°C around the coast of Iceland with the lowest coastal temperatures in the Northern part and the Northeastern part. The 98th percentile of maximum temperature in 2011 ranges from 10 to 30°C where the warmest areas are found in the Eastern part, the North-Eastern part and the Southern part of the country. The estimated increase in minimum and maximum temperatures over the years 1961 to 2009 is 0.71 and 0.47°C per decade, respectively, while the average annual temperature increased 0.24°C per decade over the same period.  相似文献   

Comparison of web plate numerical models for self‐centering steel plate shear walls          下载免费PDF全文

Patricia M. Clayton  Ching‐Yi Tsai  Jeffrey W. Berman  Laura N. Lowes 《地震工程与结构动力学》2015,44(12):2093-2110

Previous research has shown that self‐centering steel plate shear walls (SC‐SPSWs) are capable of achieving enhanced seismic performance at multiple hazard levels, including recentering following design‐level earthquakes. When modeling SC‐SPSWs numerically, these studies considered an idealized tension‐only steel plate shear wall (SPSW) web plate behavior. Research has shown that web plate behavior is more complex than predicted by the idealized model, and web plates can provide more strength, stiffness, and energy dissipation than predicted by the idealized model. The idealized model of web plate behavior is used widely in SPSW numerical models where the moment‐resisting boundary frame provides supplemental hysteretic damping and stiffness; however, in SC‐SPSWs, where the post‐tensioned boundary frame is designed to remain elastic during an earthquake, accounting for the more complex web plate behavior can have a significant impact on seismic performance estimates from numerical simulation. This paper presents different methods for modeling SC‐SPSWs. Responses from these models are compared with experimental results. A simple modification of the tension‐only model, referred to as the tension‐compression strip model, is shown to provide a reasonable approximation of SC‐SPSW behavior. Results from nonlinear response history analyses of SC‐SPSWs with the tension‐only and tension‐compression web plate models are compared to assess how the approximation of web plate behavior affects SC‐SPSW seismic performance. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献